When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CF2ClCHO_IUPAC(2008)_298K_235-370nm(rec).txt |
NAME: | chlorodifluoroacetaldehyde |
FORMULA: | CF2ClCHO |
AUTHOR(YEAR): | IUPAC(2008) |
T: | 298K |
λ: | 235-370nm(rec) |
BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species",
Atmos. Chem. Phys. 8, 4141-4496 (2008);
DOI: 10.5194/acp-8-4141-2008
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COMMENTS: | IUPAC(2008) recommendation: The preferred values for the cross-sections are those reported by O.V. Rattigan, O. Wild, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis lifetimes of halogenated aldehydes," J. Photochem. Photobiol. A: Chem. 112, 1-7 (1998); DOI: 10.1016/S1010-6030(97)00250-5 Temperature coefficients B for the parameterization ln σ(T) = ln σ(298 K) + B × (T - 298) at T = 243-298 K: ------------------
λ 104 K
(nm) (K-1)
------------------
235 -29.0
240 -17.9
245 -13.5
250 -11.8
255 -10.7
260 -10.5
265 -10.4
270 -10.5
275 -9.96
280 -10.6
285 -10.2
290 -10.6
295 -9.54
300 -10.4
305 -7.09
310 -9.73
315 -8.32
320 -7.71
325 -5.02
330 -3.03
335 -2.83
340 -2.84
345 14.0
350 37.3
355 68.1
360 75.8
365 52.9
370 63.1 |
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